Aqua­bis(4-formyl­benzoato-κ2 O 1,O 1′)bis­(isonicotinamide-κN 1)cadmium(II) monohydrate

نویسندگان

  • Tuncer Hökelek
  • Filiz Yılmaz
  • Barış Tercan
  • Ferdi Gürgen
  • Hacali Necefoğlu
چکیده

The asymmetric unit of the title Cd(II) complex, [Cd(C(8)H(5)O(3))(2)(C(6)H(6)N(2)O)(2)(H(2)O)]·H(2)O, contains two 4-formyl-benzoate (FB), two isonicotinamide (INA) ligands, one coordinated and one uncoordinated water mol-ecule; the FB ions act as bidentate ligands. The coordination number of the Cd(II) atom is seven within a CdO(5)N(2) donor set. Intra-molecular O-H⋯O hydrogen bonds link the uncoordinated water mol-ecules to the carboxyl groups. The dihedral angle between the carboxyl-ate groups and the adjacent benzene rings are 17.53 (13) and 16.55 (14)°. In the crystal structure, inter-molecular O-H⋯O, N-H⋯O, N-H⋯N and C-H⋯O hydrogen bonds link the mol-ecules into a supra-molecular structure. The amide group of one of the INA ligands is disordered over two orientations, with an occupancy ratio of 0.759 (3):0.241 (3).

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عنوان ژورنال:

دوره 65  شماره 

صفحات  -

تاریخ انتشار 2009